Search results for "Large pore"
showing 5 items of 5 documents
Synthesis of large-pore ordered mesoporous silicas containing aminopropyl groups
2005
Ordered mesoporous silicas with large-pore diameters incorporating aminopropyl groups in variable quantity have been synthesized via the co-condensation of tetraethyl orthosilicate (TEOS) and 3-tert-butyloxycarbonylaminopropyltriethoxysilane templated with nonionic surfactant P123 under acidic conditions. The deprotection of amino groups was then quantitatively achieved either by thermal treatment or acid hydrolysis followed by Et3N treatment, both routes leading to exactly the same materials. We showed that the free amino centers are fully accessible, by using the condensation of the amine function with benzaldehyde.
Gelchromatographie, die möglichkeiten verschiedener trennmaterialien
1968
Zur Gelchromatographie lassen sich organische und anorganische Trennmaterialien verwenden. Das reprasentative hochvernetzte Styragel wird benutzt, um vergleichende Untersuchungen mit porosen und Stoffen auf der Basis von Silicium und Aluminium auszufuhren. Fur die Trennung sehr hochmolekularer Substanzen, die Gele groser Porenweite erfordern, sind die anorganischen Gele wegen ihrer hohen mechanischen Stabilitat besonders geeignet. Fur Substanzen mit niedrigem Molekulargewicht sind organische und anorganische Trennstoffe hafig etwa gleich gut verwendbar, so das man den Geltyp wahlen kann, der moglichst nur hydrodynamische und keine chemische Wechselwirkung mit der Substanz zeigt. Organic and…
Increasing the stability of the Ge-containing extra-large pore ITQ-33 zeolite by post-synthetic acid treatments
2018
[EN] Extra-large pore ITQ-33 zeolite (ITT, 18 x 10 x 10-rings) is a very promising catalyst for the catalytic cracking of gasoil but, unfortunately, this material shows a limited hydrothermal stability due to the large germanium content present in the ITQ-33 structure. Taking this into account, the Ge-containing ITQ-33 has been post synthetically modified using different acid procedures with the aim of studying the effect of these treatments on the overall hydrothermal stability of this extra-large pore zeolite. In this sense, the as-prepared ITQ-33 has been treated with different HCl solutions in ethanol (from 0.1 to 1 M), containing also tetraethylorthosilicate (TEOS) as silicon precursor…
Encapsulation of folic acid in different silica porous supports: A comparative study.
2016
Although folic acid is essential to numerous bodily functions, recent research indicates that a massive exposition to the vitamin could be a double-edged sword. In this study, the capacity of different caped mesoporous silica particles (i.e. Hollow Silica Shells, MCM-41, SBA-15 and UVM-7) to dose FA during its passage through the gastrointestinal tract has been evaluated. Results confirmed that the four capped materials were capable to hinder the delivery of FA at low pH (i.e. stomach) as well as able to deliver great amounts of the vitamin at neutral pH (i.e. intestine). Nevertheless, the encapsulation efficiency and the deliver kinetics differed among supports. While supports with large p…
Performance of the cost-effective Planacon ® MCP-PMTs in strong magnetic fields
2020
Abstract We present the behavior of the cost-effective Planacon MCP-PMTs with 25 μ m pore diameter in the presence of axial magnetic fields up to 0.5 T. Having a batch of 62 devices of the same type, two MCP-PMTs were selected and their gain variation measured in different magnetic fields. These two otherwise identical devices satisfied the selection criteria by requiring the lowest (1.15 kV) and one of the highest (1.4 kV) bias voltage values to achieve a given gain. Both MCP-PMTs have a nearly identical tolerance of the strong magnetic field despite the significant difference in the bias voltage. This clarifies the mechanism of the B-field influence on the MCP-PMT gain, emphasizing the im…